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1. A 2 m3 rigid tank contains a mixture of 40% carbon dioxide and 60% acetylene by mole at 320 K and 100 bar. Determine NCO2 and pCO2 using Dalton’s Law of Additive Pressures and the VW equation of state.
2. A two-component mixture consisting of 40% carbon dioxide (1) and 60% acetylene (2) on molal basis at 320 K and 100 bar is well described by Kay’s rule and the VW equation of state. Obtain an expression for the partial molal volume CO2 and determine CO2. Use Kay’s rule.
3. A two-component mixture consisting of 40% carbon dioxide (1) and 60% acetylene (2) by mole% at 320 K and 100 bar is well described by Kay’s rule and the VW equation of state. Determine

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